Europe will have to overturn a 4 points deficit to retain the Ryder Cup.
They trail the USA 10-6 going into the final day singles at Medinah in Chicago.
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Both captains have selected most of their inform players for the early matches.
Luke Donald will lead out the European team just after 5 o’clock against Masters Champion Bubba Watson.
Rory McILroy is third out against Keegan Bradley while Graeme McDowell is in match seven against Zach Johnson.